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| Delegates to Secession Conventions | Year |
| James H. Adams | 1860 |
| James Parsons Carroll | 1860 |
| William Columbus Cauthen | 1860 |
| Robert Lafayette Crawford | 1860 |
| Joseph Brevard Kershaw | 1860 |
| James L. Orr | 1860 |
| Lewis Malone Ayer | 1861 |
| Robert Woodward Barnwell | 1861 |
| James Chestnut, Jr. | 1861 |
| Adley Hogan Gladden | 1861 |
| Christopher G. Memminger | 1861 |
| Robert Barnwell Rhett | 1861 |
| Thomas Jefferson Withers | 1861 |
| SC Delegates to Confederate Provisional Congress | Years Served |
| Robert Woodward Barnwell | 1861-1862 |
| William Waters Boyce | 1861-1862 |
| James Chestnut, Jr. | 1861-1862 |
| Laurence Massillon Keitt | 1861-1862 |
| Christopher G. Memminger | 1861-1862 |
| William Porcher Miles | 1861-1862 |
| Robert Barnwell Rhett | 1861-1862 |
| Thomas Jefferson Withers | 1861 |
| James L. Orr | 1862 |
| Confederate Senators from SC | Years Served |
| Robert Woodward Barnwell | 1862-1865 |
| James L. Orr | 1862-1865 |
| Confederate House of Representatives from SC | Years Served |
| Lewis Malone Ayer | 1862-1865 |
| Milledge Luke Bonham | 1862 |
| William Waters Boyce | 1862-1865 |
| James Farrow | 1862-1865 |
| John McQueen | 1862-1864 |
| William Porcher Miles | 1862-1865 |
| William Dunlap Simpson | 1863-1865 |
| James Hervey Witherspoon | 1864-1865 |
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